Vice President Joe Biden will be among Stephen Colbert's first "Late Show" guests next week.

He'll sit down with Colbert on Thursday, September 10th, joining previously announced guests Uber CEO Travis Kalanick and country singer Toby Keith.

Biden won't be the only political big shot on the "Late Show" stage next week.

Colbert's opening show on Tuesday will feature Republican presidential candidate Jeb Bush. (Metro Networks Inc.)